To apply for an emergency travel document, you must file Form I-131, Application for a Travel Document, complete with supporting documentation, photos and applicable fees. See the application for specific filing instructions.
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USCIS issues refugee travel documents to people with refugee or asylum status and to lawful permanent residents who obtained their Green Cards based on their refugee or asylee status.
Here's how you expedite at an acceptance facility: Fill out your DS-11 application and collect your documents. See How to Apply for more information. Be sure to include the $60 expedite fee in addition to the normal application fee.
A valid passport book is required to enter Mexico by air, and those attempting to enter at an airport with a U.S. passport card only may be denied admission.