You can arrive in the UK at any time up until the 'valid until' date, but remember that this is also the last day that you are permitted to stay in the UK.
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Equally, a standard visitor visa, provided that this is not endorsed as 'single' or 'dual-entry', can be used multiple times. This means that the visa-holder can depart and re-enter the UK as many times as they want within the visa's validity period, up to a maximum of 6 months.