You can absolutely take a private water taxi directly from the Venezia Santa Lucia train station. As you exit the station, the docks for "Motoscafi" (water taxis) are located immediately in front of you on the Grand Canal. These sleek, wooden motorboats provide the most direct and luxurious way to reach your hotel or destination, especially if your accommodation has a private pier. While significantly more expensive than the public "Vaporetto" (water bus), which costs about €9.50, a private taxi offers a door-to-door service that saves you from navigating Venice's narrow alleys and bridges with heavy luggage. In 2026, a standard transfer from the station to a city center hotel typically costs between €70 and €100 for up to 10 passengers. It is a highly recommended experience for first-time visitors who want a grand entrance into the "Floating City."