The shortest distance (air line) between Brisbane and Sydney is 455.19 mi (732.55 km). The shortest route between Brisbane and Sydney is 564.95 mi (909.21 km) according to the route planner. The driving time is approx. 10h 56min.
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In short, yes, it is absolutely worth doing a road trip from Sydney to Brisbane. If you stick to the coastline and stop at the many sunny, beachside towns along the way, there are ample National Parks and secluded beach strips for you to uncover.