Washington D.C. is generally safe for solo female travelers. However, like any other city, there are areas that are safer than others. It is advisable to stay in the well-traveled areas and to avoid walking alone at night.
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There is a reliable Washington DC police presence, especially around the main tourist areas, and violent crimes are generally very low. As a solo traveler, you'll just need to do your research to avoid dangerous areas and take extra caution when making your way through the city after dark.
Seeing the monuments at night is truly the way to go! It's beautiful at night and many people will be out doing the same thing as you so there should be no worries. If you have time The World War II Memorial is gorgeous at night. It's perfectly safe to walk the monuments at night—even at 10pm.
You can experience the nation's capital on foot in many ways. Taking a walking tour is one such way! With so much to experience, from historical buildings and monuments to parks and nature trails, it is easy to get overwhelmed by the sheer number of possibilities when exploring Washington DC.
Dupont Circle is a great and vibrant, clean location. I definitely feel safe, even late at night, but the noise level can get very bad, especially on the weekends.