Character MeetWhile not always guaranteed, you can often find Tiana and Prince Naveen at the American Pavilion in Epcot.
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Magic KingdomTiana can be found greeting guests inside Princess Fairytale Hall in Fantasyland. This is going to be your best spot to find her if she is a must meet character on your list. Other Princesses at Fairytale Hall are Cinderella, Elena, and Rapunzel.
Epcot. You can make reservations at Akershus Royal Banquet storybook dining at Epcot to meet several Princesses, including Cinderella. This delicious buffet is a favorite (and a great option if you can't get in or don't want to spend the money on Cinderella's Royal Table).
You can meet the princesses throughout World Showcase at EPCOT, each one representing a part of a real-life culture. See Mulan in China, Snow White in Germany, Jasmine in Morocco, Aurora and Belle in France, and Queen Elsa and Anna in Norway.