The metro is always safe, and 21:30 is just the start of the evening in Athens. Just take normal precautions regarding pickpockets (no wallet in back pocket etc.).
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The best way to get around Athens is on foot and by metro; most of the city's major attractions are located within walking distance or a short metro ride of one another. In fact, renting a car is little more than a nuisance, as traffic is heavy and parking is hard to find.
Very safe around that area after dark. Honestly in Greece it's less “after dark” more “after midnight” anyway. If you're the nervous type, steer away from Omonoia / Victoria but other than that, no reason around the tourist center to take anything other than regular normal precautions, even after dark.
First-timers to Athens should stay in one of the walkable, central neighborhoods with easy access to the Acropolis, Agoras, and museums. Monastiraki, Plaka, Syntagma, Psirri, Makriyanni, and the City Center are just about perfect.
Athens is known for its crazy nightlife. Greeks enjoy the night and go to bed only when the sun goes up in the morning. The city is full of bars, cafes, and clubs for every mood, style, and occasion. The visitors will surely enjoy exciting nights of fun and music.
According to recent data of crime rates across Europe's largest cities, Athens is safer than many of its contemporaries – it's statistically safer than Rome, Paris, Dublin, Brussels and Hamburg. And all of those cities are considered “safe for tourists” with crime rates low.
Is it safe to travel alone in Athens? Athens is generally considered safe for solo female travelers! I have first-hand experience in the city, and I never worry about my safety. You can look on crime sites and see for yourself that violent crime is extremely low.
Due to the numerous ancient Greek monuments that are scattered all around the area, Plaka is also known as the neighborhood of the gods. Plaka is one of the oldest neighborhoods of Athens, located right below the Acropolis Hill.
According to the study, the top five “tourist traps” in the world are the Four Corners Monument in Teec Nos Pos, Arizona, the Salem Witch Museum in Salem, Massachusetts, the Calico Ghost Town in California, Crazy Horse Memorial in Crazy Horse, South Dakota and the International UFO Museum and Research Center in Roswell ...