If you are trying to decide the best time to leave for a road trip, it is early in the morning between 5:00 am and 6:00 am. This is because there is less traffic on the roads and statistically the fewest amount of accidents during this time frame.
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While mornings and afternoons are safer, there are some exceptions. Rush hour traffic, which typically runs from 8 AM to 10 AM in the morning, and then again from 4 PM to 7 PM in the evening, plays a part in safety too. With the influx of cars at these peak times, the roads become more dangerous.
Rush Hour. Evening rush hour (between 4 and 7 p.m. weekdays) is a dangerous time to drive due to crowded roadways and drivers eager to get home after work. In winter, it's dark during rush hour, compounding an already dangerous driving situation.