The L stands for Liters. So when you see a 25L backpack, that means the capacity of the main pouch is 25 liters.
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Backpack capacity is almost always measured in liters - a universally accepted standard unit - which makes it much easier to compare backpack sizes across brands. As a rule of thumb, 25-30 liter backpacks are best for shorter weekend trips, while 30-45 liter backpacks are best for longer trips or long-term travel.
24-26 liters is considered a medium-size backpack and is probably the most popular bag capacity out there. It's great for taking to school or work, depending on the styling, and can also be a great travel pack for taking on a plane. Here is a potential packing list for that size depending on where you're headed.
A 30 litre backpack is plenty, but can be a little bit small for versatility. You need 3 changes of clothes, so that you can wash a new item each day, and have at least 2 days for it to dry.
24-26 liters is considered a medium-size backpack and is probably the most popular bag capacity out there. It's great for taking to school or work, depending on the styling, and can also be a great travel pack for taking on a plane.
40 liters is definitely big enough for traveling, as long as you're not an over-packer. It's a good idea not to go for an overly large backpack - overpacking can be as troublesome as under-packing.
Most bags range from about 30L (1,800 cubic inches) all the way to 100L+ (6,000+ cubic inches). I recommend a backpack around 40L-50L. Personally, I wouldn't go over 65L, but some people like a bigger bag.
A backpack with a capacity of around 20-30 liters should be sufficient for 11th and 12th grade students. This size can accommodate textbooks, notebooks, a laptop or tablet, and other necessary school supplies.
Larger than the 30L Travel Bag, the 40L Travel Bag is designed for longer excursions. Some might say a week, but we think you don't need much more for a month than you do for a week, so we'd definitely take this on a multi-month backpacking trip around Europe or South America (or wherever).