Most roads are less busy early in the morning, up to 7 AM, and the hours before 5 PM. These hours are less busy because workers have not hit the road to either rush to work or back home.
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While mornings and afternoons are safer, there are some exceptions. Rush hour traffic, which typically runs from 8 AM to 10 AM in the morning, and then again from 4 PM to 7 PM in the evening, plays a part in safety too. With the influx of cars at these peak times, the roads become more dangerous.
UK motorways are usually at their quietest between midnight and 6am. However, if you do travel during these times, make sure you take regular breaks. Driving on a quiet stretch of motorway over a prolonged period can make you more susceptible to fatigue.
Most crashes or near-misses happen at the times you would expect drivers to be tired: 4 to 6 a.m., midnight to 2 a.m. and 2 to 4 p.m., according to NSF. Drowsy driving puts everyone on the road at risk.