The National Highway Traffic Safety Administration (NHTSA) recommends that all children under the age of 13 ride in the back seat, ideally in the center. The rear center seat is also recommended as the best place for kids' car seats.
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If you can, put the car seat in the center seat.If not, it is fine behind either the driver or passenger side. The important thing is that it is in the back, away from the airbags. Even in a minor crash, airbags can seriously injure your little one.
Each airline will have its rules about who can sit where, but a bulkhead seat is generally considered an excellent option for families traveling with young children. The bulkhead is at the front of the cabin and sitting in those seats usually guarantees you some extra leg room.