This is why birds do not die from landing on power lines, and subway rats do not get electrocuted even if they run across the third rail; they are not bridging the energized wire or rail to a grounded part of the structure.
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If you touched the third rail and the ground, briefly (a fraction of a second), you might survive. Wikipedia claims that: Shocks above 2700 volts are often fatal, with those above 11000 volts being usually fatal. Shocks with voltages over 40,000 volts are almost invariably fatal.
Truck crashes tend to be local and less dramatic than a pile of derailed train cars on fire, even if they're deadlier. In fact, federal data shows that rail has had far fewer incidents, deaths and damage when moving hazardous materials in the U.S. than trucks.
Third rail systems are also less vulnerable to weather-related disruptions that affect overhead wires. As the third rail is on the ground it is unaffected by strong winds and less exposed to heavy snowfall.
While modern trains won't litter the tracks with human excrement, the traditional method did just that. This is what was known as a hopper toilet. It could either be a simple hole in the floor (also known as a drop chute toilet) or a full-flush system.
Do trains drop waste on the tracks? Not anymore. In the US until the 1960's, some toilets emptied directly onto the tracks. A sign was posted over the toilet reminding passengers not to flush while the train was on the station.
Federal law says that untreated sewage (even if it's been dosed with a deodorant product) can NOT be discharged in inland or coastal waters. This means the sewage from a portable toilet or a Type III holding tank can not be discharged unless you are in the ocean more than 3 miles offshore.