Yes, you can use a GPS approach at an alternate airport, but the rules depend heavily on the equipment installed in your aircraft. Under FAA regulations, if your aircraft is equipped with WAAS (Wide Area Augmentation System) compliant GPS (TSO-C145/146), you can plan for and use a GPS-based approach at your alternate airport, even if your destination also utilizes a GPS approach. However, if your aircraft only has a non-WAAS IFR-approved GPS (TSO-C129), you cannot plan for a GPS approach at both the destination and the alternate; if you plan to use a GPS approach at your destination, your alternate must have a functional ground-based navigation approach (like ILS or VOR) that you are equipped to fly. Furthermore, when planning for a WAAS-based alternate, you must use the LNAV (lateral navigation) minimums (typically 800-2) for flight planning purposes rather than the more precise LPV minimums, unless specific operational requirements are met.